Olivine-Spinel Transformation

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Experimental Determination of Spinel / Melt , Olivine / Melt

Introduction Experimental studies have identified spinels as important hosts phases for many of the highly siderophile elements (HSE) [1-4]. Yet experimental studies involving chromite or Cr-rich spinel have been lacking. Experimental studies of partitioning of HSEs between silicate, oxides and silicate melt are plagued by low solubilities and the presence of small metallic nuggets at oxygen fu...

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Revisiting the electron microprobe method of spinel-olivine-orthopyroxene oxybarometry applied to spinel peridotites

Natural peridotite samples containing olivine, orthopyroxene, and spinel can be used to assess the oxygen fugacity ( fO2) of the upper mantle. The calculation requires accurate and precise quantification of spinel Fe3+/SFe ratios. Wood and Virgo (1989) presented a correction procedure for electron microprobe (EPMA) measurements of spinel Fe3+/SFe ratios that relies on a reported correlation bet...

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Spinel–rock salt transformation in LiCoMnO4−δ

The transformation on heating LiCoMnO4, with a spinel structure, to LiCoMnO3, with a cation-disordered rock salt structure, accompanied by loss of 25% of the oxygen, has been followed using a combination of diffraction, microscopy and spectroscopy techniques. The transformation does not proceed by a topotactic mechanism, even though the spinel and rock salt phases have a similar, cubic close-pa...

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The Mg isotopic compositions of olivine, spinel, and hihonite from the Murchison carbonaceous chondrite have been determined by secondary ion mass spectrometry. The olivines exhibit only marginal effects. They have no detectable intrinsic mass fractionation; however, after correcting for mass fractionation, the mean residual 26Mg/24Mg for the five grams is slightly in excess of the terrestrial ...

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The temperature of the Icelandic mantle from olivine-spinel aluminum exchange thermometry

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ژورنال

عنوان ژورنال: Nature

سال: 1959

ISSN: 0028-0836,1476-4687

DOI: 10.1038/1831617a0